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Steric and Electronic Effects on the Interaction of Xe and Kr with Functionalized Zirconia Metal–Organic Frameworks

https://doi.org/10.1021/acsmaterialslett.1c00077

Fairchild, David C. ; Hossain, Mohammad I. ; Cordova, Jesus ; Glover, T. Grant ; Uribe-Romo, Fernando J. ( May 2021 , ACS Materials Letters)

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Effect of cleaning methods on the dissolution of diatom frustules

https://doi.org/10.1016/j.marchem.2020.103826

Saad, Emily M. ; Pickering, Rebecca A. ; Shoji, Kanaha ; Hossain, Mohammad I. ; Glover, T. Grant ; Krause, Jeffrey W. ; Tang, Yuanzhi ( August 2020 , Marine Chemistry)
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Ionic liquids of superior thermal stability. Validation of PPh 4 + as an organic cation of impressive thermodynamic durability

https://doi.org/10.1039/D0RA03220D

Soltani, Mohammad ; McGeehee, Jimmie L. ; Stenson, Alexandra C. ; O'Brien, Richard A. ; Duranty, Edward R. ; Salter, E. Alan ; Wierzbicki, Andrzej ; Glover, T. Grant ; Davis, James H. ( May 2020 , RSC Advances)

Recent work by Wasserscheid, et al. suggests that PPh 4 + is an organic molecular ion of truly exceptional thermal stability. Herein we provide data that cements that conclusion: specifically, we show that aliphatic moieties of modified PPh 4 + -based cations incorporating methyl, methylene, or methine C–H bonds burn away at high temperatures in the presence of oxygen, forming CO, CO 2 , and water, leaving behind the parent ion PPh 4 + . The latter then undergoes no further reaction, at least below 425 °C.
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